SHERWIN-WILLIAMS CO -- SILICON ALKYD ENAMEL, B56YZ237 SAFETY YELLOW --
8010-00N078087 ===================== Product Identification =====================
Product ID:SILICON ALKYD ENAMEL, B56YZ237 SAFETY YELLOW
MSDS Date:07/01/1995
FSC:8010
NIIN:00N078087
MSDS Number: CFHHL
=== Responsible Party ===
Company Name:SHERWIN-WILLIAMS CO
Address:101 PROSPECT AVE NW
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-566-2917
CAGE:54636
=== Contractor Identification ===
Company Name:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL
SPIRITS). VP:2.
CAS:64742-88-7
Fraction by Wt: 18%
OSHA PEL:100 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL
SPIRITS 140-FLASH). VP:0.5.
CAS:64742-88-7
Fraction by Wt: 4%
OSHA PEL:100 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
Ingred Name:SOLVENT NAPHTHA; (MEDIUM AROMATIC HYDROCARBONS). VP:0.1.
CAS:64742-94-5
RTECS #:WF3100000
Fraction by Wt: 1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 11%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:VOLATILE ORGANIC COMPOUNDS: 2.65 LBS/GAL.
RTECS #:9999999VO
Ingred Name:SUPP DATA:MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL
ATTENTION.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:LEVELS ARE NOT ATTAINABLE IN WORKPLACE.
REPORTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB
CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL/FATAL. (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:WARNING: PRODUCT CONTAINS CHEMICAL(S) KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER (CAL PROP 65).
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE
PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVELS ONLY(ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:DURING SANDING/ABRADING OF DRIED FILM. IF NOT
SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:ARE ACGIH TLV 10 MG/M3 (TOTAL DUST); OSHA PEL 15
MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY IRRIT &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
PROPER USE, VENT & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN &
RESP SYS. MAY CAUSE NERV SYS DEP RESS. EXTREME OVEREXP MAY RSLT IN
UNCON& POSSIBLY DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INDICATIONS OF EXCESSIVE EXPOS TO
VAPS/SPRAY MIST. REDNESS & ITCH/BURNING SENSATION MAY INDICATE
EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY
CAUSE ADVERSE EFTS TO LIVER, URINARY & REPRO SYS. RATS EXPOS TO
TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER,
SUCH EXPOS (ING 7)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:102F,39C
Lower Limits:0.2%
Upper Limits:15.3%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:COMBUST. KEEP CNTNRS TIGHTLY CLSD.
ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY
EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DOL STORAGE CATEGORY - 2. CONTENTS ARE
COMBUST. KEEP AWAY FROM HEAT & OPEN FLAME. CONSULT NFPA CODE. USE
APPRVD BONDING & GROUNDING PROCS.
Other Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO
APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY.
KEEP OUT OF REACH OF CHILDREN. USE ONLY W/ADEQ VENT. AVOID BRTHG
VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. (ING 10)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH APPRVD ORG
VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING
DRIED FILM, WEAR NIOSH APPRVD DUST/MIST RESP FOR DUST WHICH
(SUPDAT)
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. (SUPP DATA)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS
TO EXTREME HEAT. RESP PROT:MAY BE GENERATED FROM PROD, UNDERLYING
PAINTS/ABRASIVE. VENT:REFER TO OSHA STD 1910.94, 1910.107, 1910.
108. EXPLO HAZ:HOT SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS
OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS(ING 6)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>174F,>79C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.2
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:59.7
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
(40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE NUMBER. INCIN IN APPRVD FACILITY. DO NOT INCIN
CLSD CNTNR. DISP O F I/A/W FED, STATE & LOC REGS
REGARDINGPOLLUTION.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.