THE BOC GROUP,INC, BOC GASES DIV -- CARBON DIOXIDE, GAS -- 6830-01-303-4386
===================== Product Identification ===================== Product ID:CARBON DIOXIDE, GAS MSDS Date:06/07/1996 FSC:6830 NIIN:01-303-4386 Status Code:A === Responsible Party === Company Name:THE BOC GROUP,INC, BOC GASES DIV Address:575 MOUNTAIN AVE City:MURRAY HILL State:NJ ZIP:07974 Country:US Info Phone Num:908-464-8100 Emergency Phone Num:908-464-8100 Chemtrec Ind/Phone:(800)424-9300 CAGE:TO404 === Contractor Identification === Company Name:BOC GASES OF AMERICA Address:4323 BAINBRIDGE BLVD Box:City:CHESAPEAKE State:VA ZIP:23324 Country:US Phone:757-545-2486 Contract Num:SP0450-99-M-JS98 CAGE:091K6 Company Name:THE BOC GROUP,INC, BOC GASES DIV Address:575 MOUNTAIN AVE Box:City:MURRAY HILL State:NJ ZIP:07974 Country:US Phone:908-464-8100 CAGE:TO404 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Minumum % Wt:99.8 Code:F Maxumum % Wt:100. Code:F % Low Vol:99.8 % High Vol:100. OSHA PEL:9000 MG/M3;5000 PPM ACGIH TLV:9000 MG/M3;5000 PPM ACGIH STEL:54000 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: NO ADVERSE EFFECTS ANTICIPATED. SKIN: NO ADVERSE EFFECTS ANTICIPATED. INGESTION: NO ADVERSE EFFECTS ANTICIPATED. INHALATION:CARBON DIOXIDE IS THE MOST POWERFUL CEREBRAL VASODILATOR KNOWN. INHALI NGLARGE CONCENTRATIONS CAUSES RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA AND DEATH. ASPHYXIATION IS LIKELY T0 OCCUR BEFORE THE EFFECTS OF CARBON DIOXIDE OVEREXPOSURE. CHRONIC, HARMFUL EFFECTS ARE NOT KNOWN FROM REPEATED INHALATION OF LOW CONCENTRATIONS. LOW CONCENTRATIONS OF CARBON DIOXIDE CAUSE INCREASED RESPIRATION AND HEADACHE. OXYGEN DEFICIENCY DURING PREGNANCY HAS DEVELOPMENTAL ABNORMALI TIES IN HUMANS AND EXPERIMENTAL ANIMALS. Effects of Overexposure:EFFECTS OF OXYGEN DEFICIENCY RESULTING FROM SIMPLE ASPHYXIANTS MAY INCLUDE: RAPID BREATHING, DIMINISHED MENTAL ALERTNESS, IMPAIRED MUSCLAR COORDINATION, FAULTY JUDGEMENT, DEPRESSION OF ALL SENSATIONS, EMOTIONAL INSTABILITY, AND FATIGUE. AS ASPHYXIATION PROGRESSES, NAUSEA, VOMITING, PROSTRATION, AND LOSS OF CONSCIOUSNESS MAY RESULT, EVENTUALLY LEADING TO CONVULSIONS, COMA, AND DEATH. OXYGEN DEFICIE NCY DURING PREGNANCY HAS PRODUCED DEVELOPMENTAL ABNORMALITIES IN HUMANS AND EXPERIMENTAL ANIMALS. ======================= First Aid Measures ======================= First Aid:EYES: NEVER INTRODUCE OIL OR OINTMENT INTO THE EYES WITHOUT MEDICAL ADVICE. IF PAIN IS PRESENT, REFER THE VICTIM TO AN OPTHALMOLOGIST FOR FURTHER TREATMENT AND FOLLOW UP. SKIN: NO ADVERSE EFFECTS ANTI CIPATED. INGESTION: NOT ANTICIPATED. INHALATION: PROMPT MEDICAL ATTENTION MANDATORY IN ALL CASES OF OVEREXPOSURE TO CARBON DIOXIDE. RESCUERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. CONSCIOUS P ERSONS SHOULD BE QUICKLY MOVED TO FRESH AIR. UNCONSCIOUS PERSONS SHOULD BE MOVED TO FRESH AIR, GIVEN MOUTH-TO-MOUTH RESUSCITATION AND OXYGEN. FURTHER TREATMENT SHOULD BE SYMTOMATIC AND SUPPORTIVE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:NON FLAMMABLE. USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Unusual Fire/Explosion Hazard:NONE. NONFLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN USER'S EQUIPMENT, BE CERTAIN TO PURGE PIPING WITH INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN CO NTAINER OR CONTAINER VALVE, CONTACT THE APPROPRIATE EMERGENCY TELEPHONE NUMBER, 908-464-8100, OR CALL YOUR CLOSEST BOC LOCATION. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE IN WELL-VENTILATED AREAS. CO2, HEAVIER THAN AIR, WILL COLLECT IN LOW AREAS. VALVE CAPS MUST REMAIN IN PLACE UNLESS CONTAINER IS SECURED WITH VALVE OUTLET PIPED TO USE POINT. DO NOT DRAG, SLIDE, ROLL CYLINDERS. USE A HAND TRUCK. USE PRESS. REGULATOR WHEN CONNECTING TO LOWER PRESS(<3000PSIG). Other Precautions:DO NOT HEAT CYLINDERS TO INCREASE FLOW. USE CHECK VALVE OR TRAP IN DISCHARGE TO PREVENT BACKFLOW. PROTECT CYLINDERS FROM PHYSICAL DAMAGE, STORE IN COOL, DRY, WELL-VENTILATED AREA, TEMP. NOT TO EXCEED 125F (52C). STORE CYLINDERS UPRIGHT AND SECURED. SEPARATE FULL AND EMPTIES. USE " FIRST IN-FIRST OUT " INVENTORY SYSTEM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:POSITIVE PRESSURE AIR LINE WITH FULL-FACE MASK AND ESCAPE BOTTLE OR SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE. Ventilation:USE LOCAL EXHAUST TO PREVENT ACCUMULATION OF HIGH CONCENTRATIONS OF CARBON DIOXIDE. Protective Gloves:PROTECTIVE GLOVES OF ANY MATERIAL APPROPRIATE FOR THE JOB. Eye Protection:SAFETY GOGGLES OR GLASSES AS APPROPRATE FOR THE JOB. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:=-78.5C, -109.3F B.P. Text:CO2 SUBLIMES Melt/Freeze Pt:=-56.4C, -69.8F Vapor Pres:856PSIA AT 70F Vapor Density:1.53 Spec Gravity:NOT AVAILABLE pH:NOT AVAILABLE Solubility in Water:VERY SOLUBLE Appearance and Odor:A COLORLESS, ODORLESS GAS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CERTAIN REACTIVE METALS, HYDRIDES, MOIST CESIUM MONOXIDE, OR LITHIUM ACEYYLENE CARBIDE DIAMMINO MAY IGNITE. PASSING CARBON DIOXIDE OVER A MIXTURE OF SODIUM AND ALUMINUM OR MAGNESIUM MAY EXPLODE. Hazardous Decomposition Products:CARBON MOMOXIDE AND OXYGEN WHEN HEATED ABOVE 3092 F (1700C). CARBONIC ACID IS FORMED IN THE PRESENCE OF MOISTURE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:OXYGEN DEFICIENCY DURING PREGNANCY HAS PRODUCED DEVELOPMENTAL ABNORMALITIES IN HUMANS AND EXPERIMENTAL ANIMALS. EXPOSURE OF FEMALE RATS TO 60,000 PPM CO2 FOR 24 HOURS HAS PRODUCED TOXIC EFFECTS TO THE EMBRYO AND FETUS IN PREGNANT RATS. TOXIC EFFECTS TOREPRODUCTIVE SYSTEM HAVE BEEN OBSERVED IN OTHER MAMMALIAN SPECIES AT SIMILAR CONCENTRATIONS. CO2 IS THE MOST POWERFUL CEREBRAL VASODILATOR KNOWN. IN HALING LARGE CONCENTRATIONS CAUSES RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA, DEATH. CHRONIC, HARMFUL EFFECTS NOT KNOWN FROM INHALATION OF LOW (3 TO 5 MOLAR %) CONCENTRATIONS. ===================== Ecological Information ===================== Ecological:NO DATA GIVEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF RESIDUAL WASTE OR UNUSED QUANTITIES. RETURN IN THE SHIPPING CONTAINER PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE TO BO C GASES OR AUTHORIZED DISTRIBUTOR FOR PROPER DIAPOSAL. =================== MSDS Transport Information =================== Transport Information:DOT: PROPER SHIPPING NAME: CARBON DIOXIDE, HAZARD CLASS 2.2, UN 1013, LABEL, NONFLAMMABLE GAS. CANADA TDG: PROPER SHIPPING NAME: CARBON DIOXIDE, HAZARD CLASS 2.2, UN 1013, LABEL, NONFLAMMABLE GAS.... ... ===================== Regulatory Information ===================== SARA Title III Information:ACUTE HEALTH HAZARD. SUDDEN RELEASE OF PRESSURE HAZARD. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.