Page 1/7 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 22.02.2008 Revision: 22.02.2008 1Identification of the substance/preparation and of the company/undertaking · Product details · Trade name: Gleitspray FLC 1012 · Application of the substance / the preparation Lubricant · Manufacturer/Supplier: Chemie-Technik GmbH ELKALUB Hochleistungs-Schmierstoffe Robert-Bosch-Straße 19 D-72189 Vöhringen Deutschland / Germany Telefon / Phone: (++49) 07454/9652-0 Fax: (++49) 07454-965235 E-mail: info@chemietechnik.com www.chemietechnik.com · Further information obtainable from: Geschäftsleitung / Management Telefon / Phone: (++49) 07454/9652-0 · Information in case of emergency: Geschäftsleitung / Management Telefon / Phone: (++49) 07454/9652-0 2Hazards identification · Hazard description: F+ Extremely flammable · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Warning! Pressurized container. R 12 Extremely flammable. R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition -No smoking. Buildup of explosive mixtures possible without sufficient ventilation. Keep out of the reach of children · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. 3Composition/information on ingredients · Chemical characterization · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: CAS: 106-97-8 EINECS: 203-448-7 butane F+; R 12 10-25% CAS: 64742-49-0 EINECS: 265-151-9 Naphtha (petroleum), hydrotreated light Xn, Xi, F, N; R 11-38-51/53-65-67 10-25% CAS: 74-98-6 EINECS: 200-827-9 propane F+; R 12 10-25% (Contd. on page 2) GB Page 2/7 Revision: 22.02.2008 (Contd. of page 1) Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 22.02.2008 Trade name: Gleitspray FLC 1012 · Additional information: For the wording of the listed risk phrases refer to section 16. CAS: 68425-15-0 EINECS: 270-335-7 Polysulfides, di-tert-dodecyl R 53 2.5-10% CAS: 68649-42-3 EINECS: 272-028-3 Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts Xi, N; R 38-41-51/53 = 2.5% CAS: 75-28-5 EINECS: 200-857-2 isobutane F+; R 12 = 2.5% CAS: 110-54-3 EINECS: 203-777-6 n-hexane Xn, Xi, F, N; R 11-38-48/20-62-51/53-65-67 = 2.5% CAS: 80939-62-4 EINECS: 279-632-6 Amines, C11-14-branched alkyl, monohexyl and dihexyl phosphates Xi, N; R 36/38-51/53 = 2.5% CAS: 80595-74-0 EINECS: 279-514-4 N,N-bis(2-ethylhexyl)-5-methyl-1H-benzotriazole-1-methylamine Xi, N; R 38-43-51/53 < 0.15% CAS: 80584-90-3 EINECS: 279-503-4 N,N-bis(2-ethylhexyl)-4-methyl-1H-benzotriazole-1-methylamine Xi, N; R 38-43-51/53 < 0.15% 4First aid measures ·Generalinformation: Takeaffectedpersonsoutintothefreshair. Donotleaveaffectedpersonsunattended. ·Afterinhalation:Supplyfreshair;consultdoctorincaseofcomplaints. ·Afterskincontact: Generallytheproductdoesnotirritatetheskin. Washwithwaterandsoap ·Aftereyecontact:Rinseopenedeyeforseveralminutesunderrunningwater. ·Afterswallowing:Donotinducevomiting;callformedicalhelpimmediately. 5Firefighting measures ·Suitableextinguishingagents: CO2,powderorwaterspray.Fightlargerfireswithwatersprayoralcoholresistantfoam. ·Forsafetyreasonsunsuitableextinguishingagents:Waterwithfulljet ·Specialhazardscausedbythesubstance,itsproductsofcombustionorresultinggases: Riskofburstingincaseoffireheat ·Protectiveequipment:Wearself-containedrespiratoryprotectivedevice. ·AdditionalinformationCoolendangeredreceptacleswithwaterspray. 6Accidental release measures ·Person-relatedsafetyprecautions: Wearprotectiveequipment.Keepunprotectedpersonsaway. EnsureadequateventilationParticulardangerofslippingonleaked/spilledproduct. ·Measuresforenvironmentalprotection:Donotallowtoentersewers/surfaceorgroundwater. ·Measuresforcleaning/collecting: Ensureadequateventilation. Absorbwithliquid-bindingmaterial(sand,diatomite,acidbinders,universalbinders,sawdust). GB(Contd.onpage3) Printing date 22.02.2008 Safety Data Sheet according to 1907/2006/EC, Article 31 Page 3/7 Revision: 22.02.2008 Trade name: Gleitspray FLC 1012 (Contd. of page 2) 7Handling and storage · Handling: · Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. · Information about fire -and explosion protection: Keep ignition sources away -Do not smoke. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C, i.e. electric lights. Do not pierce or burn, even after use. Do not spray onto a naked flame or any incandescent material. · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool location. Observe official regulations on storing packagings with pressurized containers. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. · Recommended storage temperature: 15 -35°C, max. 50°C 8Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · Ingredients with limit values that require monitoring at the workplace: 106-97-8 butane WEL Short-term value: 1810 mg/m³, 750 ppm Long-term value: 1450 mg/m³, 600 ppm Carc (if more than 0.1% of buta-1.3-diene) 64742-49-0 Naphtha (petroleum), hydrotreated light TWA (8H) Long-term value: 1000 mg/m³, 250 ppm 110-54-3 n-hexane WEL Long-term value: 72 mg/m³, 20 ppm · Additional information: The lists valid during the making were used as basis. · Personal protective equipment: · General protective and hygienic measures: Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. · Respiratory protection: Not necessary if room is well-ventilated. · Protection of hands: · Material of gloves If contamination is possible, use gloves made of nitrile according EN 374 · Penetration time of glove material > 480 min / 0,4 mm thickness · Eye protection: Safety glasses in case of spittings 9Physical and chemical properties · General Information Form: Colour: Odour: Aerosol Yellowish Characteristic (Contd. on page 4) GB Page 4/7 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 22.02.2008 Revision: 22.02.2008 Trade name: Gleitspray FLC 1012 (Contd. of page 3) · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: -44°C · Flash point: Not applicable, as aerosol. · Ignition temperature: 250°C · Self-igniting: Product is not selfigniting. · Danger of explosion: Risk of bursting at temperatures > 50°C. Damage of the container may lead to the formation of explosive mixtures of gas/vapors with air. · Explosion limits: Lower: 0.8 Vol % Upper: 10.9 Vol % Pressure (20°C) 2 -4 bar · Density at 20°C: 0.75 g/cm³ · Solubility in / Miscibility with water: Not miscible or difficult to mix. · Solvent content: Organic solvents: 14.3 % VOC (EC) 43.75 % · Additional information Vapors are heavier than air. 10Stability and reactivity · Thermal decomposition / conditions to be avoided: Risk of bursting at temperatures >50°C. · Dangerous reactions No dangerous reactions known. · Dangerous decomposition products: In case of fire the formation of toxic gases is possible. · Additional information: Stable for a storage time of min. 24 months 11Toxicological information · Acute toxicity: · LD/LC50 values relevant for classification: 64742-49-0 Naphtha (petroleum), hydrotreated light Oral Dermal Inhalative LD50 LD50 LC50/4 h > 5000 mg/kg (rat) > 2000 mg/kg (rabbit) > 20 mg/l (rat) · Primary irritant effect: · on the skin: low irritant -no duty to declare · on the eye: No irritating effect. low · Sensitization: Sensitizing effect by skin contact is possible by prolonged exposure. GB (Contd. on page 5) Page 5/7 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 22.02.2008 Revision: 22.02.2008 Trade name: Gleitspray FLC 1012 (Contd. of page 4) GB 12 Ecological information · Ecotoxical effects: · Acquatic toxicity: 64742-49-0 Naphtha (petroleum), hydrotreated light LC 50 / 96 h 2.5 mg / l (Flathead Minnow /Elritze) · Remark: Harmful to fish · General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Harmful to aquatic organisms 13 Disposal considerations · Product: · Recommendation empty cans: material recycling filled cans: remove in accordance with local regulations · European waste catalogue 16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST 16 05 00 gases in pressure containers and discarded chemicals 16 05 04 gases in pressure containers (including halons) containing dangerous substances · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. 14 Transport information · Land transport ADR/RID (cross-border) · ADR/RID class: 2 5F Gases. · Danger code (Kemler): 23 · UN-Number: 1950 · Packaging group: - · Hazard label: 2.1 · Description of goods: 1950 AEROSOLS · Remarks: Transportation as "LIMITED QUANTITIES" (LQ2) according 3.4 ADR possible. Sole marking: UN 1950 (rhombe) Entry in the transportation document: Transportation according chapter 3.4 ADR · Maritime transport IMDG: · IMDG Class: 2.1 · UN Number: 1950 · Label 2.1 · Packaging group: - (Contd. on page 6) Page 6/7 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 22.02.2008 Revision: 22.02.2008 Trade name: Gleitspray FLC 1012 (Contd. of page 5) · EMS Number: F-D,S-U · Marine pollutant: No · Proper shipping name: AEROSOLS · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: 2.1 · UN/ID Number: 1950 · Label 2.1 · Packaging group: - · Proper shipping name: AEROSOLS, flammable 15Regulatory information · Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. · Code letter and hazard designation of product: F+ Extremely flammable · Risk phrases: 12 Extremely flammable. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Safety phrases: 23 Do not breathe vapour/spray. 24/25 Avoid contact with skin and eyes. 35 This material and its container must be disposed of in a safe way. 51 Use only in well-ventilated areas. · Special labelling of certain preparations: Contains N,N-bis(2-ethylhexyl)-4-methyl-1H-benzotriazole-1-methylamine, N,N-bis(2-ethylhexyl)-5-methyl- 1H-benzotriazole-1-methylamine. May produce an allergic reaction. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition -No smoking. Buildup of explosive mixtures possible without sufficient ventilation. Keep out of the reach of children · National regulations: · Information about limitation of use: Employment restrictions concerning juveniles must be observed. Class Share in % I = 2,5 NK 10-25 16Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant R-phrases 11 Highly flammable. 12 Extremely flammable. (Contd. on page 7) GB Page 7/7 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 22.02.2008 Revision: 22.02.2008 Trade name: Gleitspray FLC 1012 (Contd. of page 6) 36/38 Irritating to eyes and skin. 38 Irritating to skin. 41 Risk of serious damage to eyes. 43 May cause sensitisation by skin contact. 48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 53 May cause long-term adverse effects in the aquatic environment. 62 Possible risk of impaired fertility. 65 Harmful: may cause lung damage if swallowed. 67 Vapours may cause drowsiness and dizziness. GB