MARTIN-SENOUR CO DIV SHERWIN-WILLIAMS CO -- TOUGH COAT ALKYD ENAMEL,
727-1519 GLOSS GREEN -- 8010-00N081341 ===================== Product Identification =====================
Product ID:TOUGH COAT ALKYD ENAMEL, 727-1519 GLOSS GREEN
MSDS Date:01/03/1994
FSC:8010
NIIN:00N081341
MSDS Number: CGBBX
=== Responsible Party ===
Company Name:MARTIN-SENOUR CO DIV SHERWIN-WILLIAMS CO
Box:6709
City:CLEVELAND
State:OH
ZIP:44101
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-566-2917
CAGE:MART2
=== Contractor Identification ===
Company Name:MARTIN-SENOUR CO
Address:101 PROSPECT AVE N.W.
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Phone:216-566-2902
CAGE:MART2
Company Name:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS). VP:
2.0
CAS:64742-47-8
RTECS #:OA5504000
Fraction by Wt: 40%
OSHA PEL:100 STEL (MFR)
ACGIH TLV:100 STEL (MFR)
Ingred Name:SOLVENT NAPHTHA, PETROLEUM, MEDIUM ALIPHATIC; (MINERAL
SPIRITS, 140-FLASH). VP: 2.0
CAS:64742-88-7
RTECS #:WF3450000
Fraction by Wt: 40%
OSHA PEL:100 STEL (MFR)
ACGIH TLV:100 STEL (MFR)
Ingred Name:XYLENE (SARA 313) (CERCLA). VP: 7.1
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 1%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 9%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9495
Ingred Name:VOLATILE ORGANIC COMPOUNDS (VOC) - 3.71 LBS/GAL
RTECS #:9999999VO
Ingred Name:WASTE DISP METH:LOCAL REGULATIONS REGARDING POLLUTION.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), OSHA PEL 15 MG/M3 (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:(TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION). KEEP
AWAY FROM HEAT, SPARKS, & OPEN FLAME. VAPS WILL (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE &
UNTIL ALL VAPS ARE GONE:KEEP AREA VENT-DO NOT (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:SMOKE-EXTINGUISH ALL FLAMES, PILOT LIGHTS, &
HEATERS-TURN OFF STOVES, ELECTRIC TOOLS & APPLICANCES, & (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODES. USE
APPRVD BONDING & GROUNDING PROC. KEEP CNTNR CLOSED (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS
W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:KEEP OUT OF THE REACH OF CHILDREN. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:CONTENTS CAN BE HARMFUL OR FATAL.
RTECS #:9999999ZZ
Ingred Name:RESP PROT:RESP (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
RTECS #:9999999ZZ
Ingred Name:VENT:LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107,
1910.108.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:EVIDENCE TO INDICATE IT CAUSES BIRTH
DEFECTS IN HUMANS. RATS EXPOSED TO TITANIUM DIOXIDE DUST (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH
EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED
OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN
UNCONSCIOUSNESS & POSS DEATH. SIGNS & SYMPS OF OVEREXP: HDCH, DIZZ,
NAUS, & LOSS OF COORDINATION ARE I NDICATION OF EXCESSIVE EXPOS TO
VAPS/SPRAY MISTS. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:EYE/EXCESSIVE SKIN EXPOS.
CHRONIC:PRLNGD OVEREXP TO SOLV INGS IN ING SECTION MAY CAUSE
ADVERSE EFTS TO THE LIVER & URINARY SYS. ETHYLENE GLYCOL IS
CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH
DEFECTS IN RATS & MICE AT HIGH DOSES WHEN GIVEN IN DRINKING
WATER/BY GAVAGE. THERE IS NO (ING 17)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATERFOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:>99F,>37C
Lower Limits:1.0%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF.
H*2O MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE
WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE ONLY WITH ADEQUATE VENTILATION.
AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND
EYES.
Other Precautions:THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE
PARTICULATES (LISTED 'AS DUST' IN ING SECTION) WHICH MAY BE PRESENT
AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF THE DRIED FILM. IF NO
SPECIFIC DU STS ARE LISTED IN ING SECTION, (ING 7)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP
APPRVD BY NIOSH FOR PROT AGAINST MATLS IN ING SECTION. WHEN
SANDING/ABRADING THE DRIED FIL M, WEAR A NIOSH APPRVD DUST/MIST(ING
15)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF THE EXPOS TO MATLS
IN ING SECTION IS MAINTAINED BELOW APPLICABLE EXPOS (ING 16)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNITION/EXPLOSION
WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:HOT SURF REQ SPECIAL PREC.
DURING EMER CNDTNS OVEREXP TO DECOMP PROD MAY CAUSE A HLTH HAZ.
SYMPS MAY NOT BE IMMED APPARENT. OBTAINMED ATTN. MATLS TO
AVOID:DANGEROUSLY INCRD PRESS IN CLSD CNTNRS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>284F,>140C
Vapor Pres:SEE ING
Vapor Density:HVR/AIR
Spec Gravity:0.98
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
FOR CHROME ALUMINIUM ONLY-CONTAM W/H*2O, ACIDS/ALKALIS CAN CAUSE
EVOLUTION OF HYDROGEN, WHICH MAY RSLT IN (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZS AS DEFINED
UNDER THE RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM THE APPLIC EPA HAZS WASTE NUMBER. INCIN IN APPRVD FACILITY.
DO NOT INCIN CLSD C NTNR. DISPOSE OF I/A/W/FED, STATE & (ING 6)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.