SHERWIN-WILLIAMS CO -- B56 BZ 11 BLACK SILICONE ALKYD ENAMEL --
8010-00F053397 ===================== Product Identification =====================
Product ID:B56 BZ 11 BLACK SILICONE ALKYD ENAMEL
MSDS Date:07/01/1995
FSC:8010
NIIN:00F053397
MSDS Number: CDRHM
=== Responsible Party ===
Company Name:SHERWIN-WILLIAMS CO
Address:101 PROSPECT AVE N W
City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Info Phone Num:216-566-2902/216-566-2917
Emergency Phone Num:216-566-2917/216-566-2902
CAGE:54636
=== Contractor Identification ===
Company Name:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES
MINERAL SPIRITS *96-4*
CAS:64742-88-7
Fraction by Wt: 24%
Other REC Limits:100 PPM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:HEAVY AROMATIC SOLVENT NAPHTHA PETROLEUM *96-4*
CAS:64742-94-5
RTECS #:WF3100000
Fraction by Wt: 2%
Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS
(IARC CARC GROUP 3) - *96-4*
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 2%
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/CUM
ACGIH TLV:3.5 MG/CUM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE IRRITATION OF EYES, SKIN &
RESPIRATORY SYSTEM. MAY CAUSE CNS DEPRESSION. EXTREME OVEREXPOSURE
MAY RESULT IN UNCONSCIOUSNESS & POSSIBLY DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE,
DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING
SENSATION
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM AREA. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN/EYES: WASH THOROUGHLY W/SOAP & WATER. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:102F
Lower Limits:0.8
Upper Limits:15.3
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT INCLUDING SCBA.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. (SUPP)
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE DUE TO EXTREME HEAT. (SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. REMOVE W/INERT
ABSORBENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTENTS ARE COMBUSTIBLE. KEEP AWAY
FROM HEAT & OPEN FLAME. USE APPROVED GROUNDING & BONDING
PROCEDURES. KEEP CONTAINER CLOSED WHEN NOT IN USE. (SUPP)
Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING CAN BE HARMFUL/FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE CAN'T BE CONTROLLED BELOW APPLICABLE
LIMITS BY VENTILATION, WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. WEAR DUST/MIST
RESPIRATOR APPROVED BY NIOSH/MS HA WHEN SANDING/ABRADING DRIED
FILM.
Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST IS ACCEPTABLE IF
EXPOSURE IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
Protective Gloves:RECOMMENDED
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. KEEP OUT OF REACH OF CHILDREN.
Supplemental Safety and Health
UNUSUAL FIRE: APPLICATION TO HOT SURFACE REQUIRE SPECIAL PRECAUTION.
SPECIAL FIRE: WATER MAY BE USED TO COOL CLOSED CONTAINERS TO
PREVENT PRESSURE BUILD-UP & POSSIBLE AUTOIGNITION/EXPLOSION DUE TO
EXT REME HEAT. EYE PROTECTION: SAFETY SPECTACLES W/UNPERFORATED
SIDESHIELDS. HANDLING/STORAGE: DON'T TAKE INTERNALLY.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:174-416F
Vapor Density:>1
Spec Gravity:0.96-1.24
VOC Grams/Liter:2.68
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:40-58
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:FIRE: CO2, CO
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN AN APPROVED FACILITY. DON'T
INCINERATE CLOSED CONTAINER. DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.