3M COMPANY -- 3M BRAND GLASS CLEANER CONCENTRATE ======================================================= MSDS Safety Information ======================================================= FSC: 7930 NIIN: 01-381-5826 MSDS Date: 08/15/1996 MSDS Num: CDHJV Product ID: 3M BRAND GLASS CLEANER CONCENTRATE MFN: 01 Responsible Party Cage: 76381 Name: 3M COMPANY Address: 3M CTR City: ST. PAUL MN 55144-1000 Info Phone Number: 612-733-1110 Emergency Phone Number: 612-733-1110 Published: Y ======================================================= Contractor Summary ======================================================= Cage: 76381 Name: MINNESOTA MINING AND MFG CO, DBA 3M Address: 3M CENTER BLDG 224-5S-04 City: SAINT PAUL MN 55144-1000 Phone: 866-556 5712 / 612-733-1110 ======================================================= Item Description Information ======================================================= Item Manager: GSA Item Name: GLASS CLEANER Unit of Issue: BX Quantitative Expression: 00000000006EA UI Container Qty: 1 ======================================================= Ingredients ======================================================= Cas: 7732-18-5 RTECS #: ZC0110000 Name: WATER % Wt: 60-90 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Name: SURFACTANT % Wt: 5-10 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ----------------------------- Cas: 64-19-7 RTECS #: AF1225000 Name: ACETIC ACID (CERCLA) % Wt: 1-5 Other REC Limits: NONE RECOMMENDED OSHA PEL: 10 PPM ACGIH TLV: 10 PPM/STEL 15 EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 110615-47-9 Name: ALKYL GLUCOPYRANOSE OLIGONERS % Wt: 1-5 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ----------------------------- Cas: 68515-73-1 Name: GLUCOPYRANOSE GLYCOCIDE OLIGOMERS % Wt: 1-5 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Name: FRAGRANCE % Wt: 1-5 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ----------------------------- Cas: 112-34-5 RTECS #: KJ9100000 Name: DIETHYLENE GLYCOL BUTYL ETHER % Wt: 1-5 Other REC Limits: 35 PPM MFR REC OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ALLERGIC SKIN REACTION, KIDNEY/LIVER EFFECTS, LUNG DAMAGE. INGESTION: GI TISSUE IRRITATION.MOD IRIT.SEVERE SKIN IRRIT/ABSORPTION/CNS DEPRESSION.UPPER RESP IRRIT. Signs And Symptions Of Overexposure: SKIN: RED/SWELL/BLISTER/ITCH/DRYNESS/CRACKING/PAIN/ABSORPTION. EYE: RED/PAIN/SWELL/TEAR/HAZY VISION. INHALATION: HEADACHE/DIZZY/DROWSY/UNCOORDINATED/SLURRED SPEECH/GIDDY/UNCONSCIOUS. SORE NOSE/THROAT, COUGH/SNEEZE. LESS URINE/BLOODY URINE/BACK PAIN. JAUNDICE, UPPER ABDOMIN TENDERNESS.COUGH/DIFF BREATHE/WHEEZE/CHEST** Medical Cond Aggravated By Exposure: **TIGHTNESS/CONGESTION/COUGHING BLOOD. INGEST:PAIN/VOMIT/ABDOM TENDER/NAUSEA/BLOODY VOMIT/FECES. First Aid: EYES: IMMED FLUSH W/LARGE AMTS WATER >15MIN. GET IMMED MED AID. SKIN: IMMED FLUSH W/LARGE AMTS WATER. REMOVE CONTAM CLOTHES. WASH CONTAM CLOTHES BEFORE REUSE. CALL DR. INHALATION: GET FRESH AIR. CALL DR. INGESTION: DON'T INDUCE VOMITING. GIVE 2 GLASSES WATER. CALL DR. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VENTILATE AREA. EXTINGUISH ALL IGNIT SOURCES. CONTAIN SPILL. COVER W/ABSORBENT. COLLECT SPILLED MAT'L. CLEAN UP RESIDUE W/WATER. PLACE IN CLOSED CONTAINER. Waste Disposal Methods: <5GL: DISCHARGE TO WASTE WATER TREATMENT SYSTEM. INCINERATE IN A PERMITTED HAZARDOUS WASTE INCINERATOR. DISPOSE OF COMPLETELY ABSORBED WASTE PRODUCT IN HAZARDOUS WASTE FACILITY. Handling And Storage Precautions: STORE AWAY FROM HEAT. KEEP CONTAINER IN WELL-VENTILATED AREA. Other Precautions: KEEP CONTAINER TIGHTLY CLOSED & AWAY FROM HEAT/SPARKS/OPEN FLAME/OTHER IGNIT SOURCES. COMBUSTIBLE LIQUID & VAPOR. DILLUTE MATERIAL. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: >200F,>93C Lower Limits: NOT EST. Upper Limits: NOT EST. Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM, ALCOHOL-TYPE FOAM. Fire Fighting Procedures: WEAR FULL PROTECT CLOTHES: HELMET, POS PRESSURE/PRESSURE DEMAND SCBA, BUNKER COAT/PANTS, BANDS AROUND ARMS/WAIST/LEGS, FACE-MASK. PROTECT EXPOSED AREAS OF HEAD. Unusual Fire/Explosion Hazard: NONE ANTICIPATED ======================================================= Control Measures ======================================================= Respiratory Protection: AVOID INHALATION. USE HALF-MASK ORGANIC VAPOR RESPIRATOR OR ACID GAS RESPIRATOR NIOSH APPROVED Ventilation: LOCAL EXHAUST VENTILATION. Protective Gloves: BUTYL/RUBBER Eye Protection: VENTED GOGGLES Other Protective Equipment: COVERALLS. Work Hygienic Practices: WASH HANDS AFTER HANDLING/BEFORE EATING. DON'T INGEST. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: NOT EST. M.P/F.P Text: NA Vapor Pres: NOT EST. Vapor Density: NOT EST. Volatile Org Content %: 10 Spec Gravity: 1.0 PH: 3.5 Viscosity: 10 CPS Evaporation Rate & Reference: NOT EST. Solubility in Water: COMPLETE Appearance and Odor: LIQUID, DARK BLUE COLOR, STRONG FRAGRANCE Percent Volatiles by Volume: 90.0 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, IRRITANT VAPORS OR GASES. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: VOC = 10% ======================================================= Transportation Information ======================================================= Responsible Party Cage: 76381 Trans ID NO: 131964 Product ID: 3M BRAND GLASS CLEANER CONCENTRATE MSDS Prepared Date: 08/15/1996 Review Date: 02/27/1997 MFN: 1 Multiple KIT Number: 0 Review IND: Y Unit Of Issue: BX Container QTY: 1 ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: 3M BRAND GLASS CLEANER CONCENTRATE Cage: 76381 Company Name: MINNESOTA MINING AND MFG CO, DBA 3M Street: 3M CENTER BLDG 224-5S-04 City: SAINT PAUL MN Zipcode: 55144-1000 Health Emergency Phone: 612-733-1110 Label Required IND: Y Date Of Label Review: 10/12/1999 Status Code: A Origination Code: G Hazard And Precautions: ALLERGIC SKIN REACTION, KIDNEY/LIVER EFFECTS, LUNG DAMAGE. INGESTION: GI TISSUE IRRITATION.MOD IRIT.SEVERE SKIN IRRIT/ABSORPTION/CNS DEPRESSION.UPPER RESP IRRIT. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.